This is the tank with the top cut off and after removing a couple of inches of the foam lagging:

I reckon the 117l cylinder will have at least 90l left after removing the top, even without a syphon effect outlet.
The metal is very thin - you can easily flex the rim with one finger and I'm sure it would be very easy to dent. If this were a boiler, being upended and cleaned out regularly and so on, I'd definately want to re-inforce the rim somehow, but as a HLT (which I'll probably leave more or less alone aside from filling and emptying) it may be okay as is - not decided yet.
I had originally intended to use the cylinder upside down and cut the bottom off instead, to make use of the existing immersion setup. However, the immersion was locked solid and seemed to have suffered some sort of burn out. More importantly though it was almost vertical - smaller batches and the latter part of sparges would leave it sticking out of the water as this photo shows:

So I'm now going to use it the right way up and put an immersion in horizontally, towards the bottom somewhere.
This is the inside, with the coil which i'll remove next:

I'm thinking of using the upper coil hole to poke a temperature sensor in. I may use the lower one as the drain or sight tube connection, but its a little high. There's also the original connection for the cold water feed lower down.
There's a bit of green and some scale but its not too bad at all. The metal is quite smooth inside so hopefully will clean up fairly well. I'll probably use a scratch-free kitchen scrubber, and possibly some cleaning fluid if I can find anything reasonably powerful yet also okay for copper.
Thats all for now

Cheers
Kev